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Creators/Authors contains: "Tanaka, Joji"

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  1. ; ; (, Polymer Chemistry)
    Here we report the modelling of thermally initiated RAFT step-growth polymerization kinetics of maleimide and acrylate monomers with bifunctional RAFT agents bearing tertiary carboxyalkyl-stabilized fragmentable R groups. 
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    Free, publicly-accessible full text available January 14, 2026
  2. ; ; ; (, Polymer Chemistry)
    Here, we report the modelling of photo-mediated RAFT step-growth polymerization kinetics of maleimide and acrylate monomers with bifunctional RAFT agents bearing tertiary carboxyalkyl stabilized fragementable R groups. 
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    Free, publicly-accessible full text available January 1, 2026
  3. ; ; ; (, Macromolecular Rapid Communications)
    Abstract Photomediated reversible addition fragmentation chain transfer (RAFT) step‐growth polymerization is performed using a trithiocarbonate‐based chain transfer agent (CTA) and acrylate‐based monomers both with and without a photocatalyst. The versatility of photo‐mediated RAFT step‐growth is demonstrated by one‐pot synthesis of a graft copolymer via sequential monomer addition. Furthermore, oxygen‐tolerant photo‐mediated RAFT step‐growth is demonstrated, facilitated by the appropriate selection of photocatalyst and solvent pair (zinc tetraphenyl porphyrin [ZnTPP] and dimethyl sulfoxide [DMSO]), enabling ultralow volume polymerization under open‐air conditions. 
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    Free, publicly-accessible full text available January 1, 2026
  4. ; ; ; (, Polymer Chemistry)
    Here we report one-pot stimuli-responsive tandem degradation of a graft copolymer with alternating backbone functionalities. 
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  5. ; ; ; ; ; ; ; (, Chemical Science)
    RAFT step-growth polymerizationviathe Z-group approach was developed, offering a facile method to prepare deconstructable (multiblock) polymers by combining RAFT chain-growth polymerization and RAFT interchange. 
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  6. ; ; ; ; (, ACS Macro Letters)
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  7. ; ; ; (, Chemical Communications)
    RAFT step-growth polymerization is an emerging method that synergistically combines the benefits of RAFT polymerization (functional group and user-friendly nature) and step-growth polymerization (versatility of the polymer backbone). 
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  8. ; ; ; ; (, Polymer Chemistry)
    Demonstrated is the successful A 2 + B 2 RAFT step-growth polymerization of bis-acrylamides using a bifunctional trithiocarbonate chain transfer agent as the comonomer. Remarkably, homopropagation typical of acrylamides leading to branching and crosslinking was not observed. Moreover, synthesized poly(acrylamides) can be degraded by simply adding excess ethanolamine or PBu 3 . 
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  9. ; ; (, Polymer Chemistry)
    Photomediated RAFT step-growth polymerization was performed with and without the presence of a photocatalyst using a trithiocarbonate-based CTA and a maleimide monomer. Under catalyst-free conditions, the polymerization proceeded with an appreciable rate under irradiation with blue and green light, which was extended to red light in the presence of ZnTPP. 
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  10. ; ; ; ; (, ACS Macro Letters)
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